Hydration of propene over acidic zeolites

Autor:	M. H. W. Sonnemans
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Propene Acid strength chemistry.chemical_compound Competitive adsorption Chemistry Process Chemistry and Technology Diffusion Inorganic chemistry Zeolite Catalysis
Zdroj:	Applied Catalysis A: General. 94:215-229
ISSN:	0926-860X
DOI:	10.1016/0926-860x(93)85009-e
Popis:	A study of the hydration of propene over acidic zeolites shows that the catalytic activities of H-mordenite and stabilised H- (VUS-)Y are determined by their effective Bronsted acidity (i.e. the concentration of acid sites multiplied by their acid strength). For H-ZSM-5 it has been established that the rate of propene hydration is: (i) significantly influenced by competitive adsorption of propene and water, and (ii) limited by intracrystalline diffusion. Water inhibits the rate of hydration, this effect being more pronounced for H-ZSM-5 than for the other two zeolites. During propene hydration the interior of the zeolite becomes rapidly inaccessible due to the formation of carbonaceous compounds resulting from propene oligomerisation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6bc4a5e223e01d59ddd1d020d6ef7d89 https://doi.org/10.1016/0926-860x(93)85009-e Zobrazit plný text záznamu