A new method for the synthesis of organometallic derivatives of the transition metals in their lowest oxidation states

Autor:	B. A. Dolgoplosk, L.Sh. Guzman, E. I. Tinyakova, S.I. Beilin, S.B. Golstein
Rok vydání:	1977
Předmět:	Inorganic Chemistry Tris chemistry.chemical_compound chemistry Transition metal Organic Chemistry Inorganic chemistry Materials Chemistry chemistry.chemical_element Halide Physical and Theoretical Chemistry Biochemistry Titanium
Zdroj:	Journal of Organometallic Chemistry. 142:145-148
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)94335-3
Popis:	The exchange reactions of organotitanium(IV) compounds with alkyllithiums have been investigated; tris(trimethylsilylmethyl)titanium and tribenzyltitanium have been synthesized. It is shown that this method may be used for the synthesis of compounds of the transition metals in their lowest oxidation states, and excludes the stage of organometal halide formation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6baa533df403b0ba0559b940f93b1c8e https://doi.org/10.1016/s0022-328x(00)94335-3 Zobrazit plný text záznamu