Molecular interactions of some non-essential amino acids in aqueous solutions of 1-methylimidazolium chloride at different temperatures
| Autor: | Ashish Kumar, Rekha Gaba, Amalendu Pal, Dinkar Sharma, Harsh Kumar |
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| Rok vydání: | 2019 |
| Předmět: |
Aqueous solution
Isentropic process Chemistry Solvation Analytical chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Chloride Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials Dilution Molar volume Speed of sound Materials Chemistry medicine Physical and Theoretical Chemistry 0210 nano-technology Ternary operation Spectroscopy medicine.drug |
| Zdroj: | Journal of Molecular Liquids. 279:711-718 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2019.01.094 |
| Popis: | Densities and speeds of sound of l ‑glutamic acid and l ‑aspartic acid in aqueous and aqueous solution of 1-methylimidazolium chloride [mim][Cl] have been measured at T = (288.15, 298.15 and 308.15) K under atmospheric pressure. The apparent molar volumes (Vϕ), apparent molar volume at infinite dilution (Vϕ0), apparent molar isentropic compression (Kϕ, S) and the apparent molar isentropic compression at infinite dilution (Kϕ, S0) have also been computed from density and speed of sound data. Furthermore, limiting apparent molar expansion, Eϕ0, and hydration numbers, nH have been evaluated to support the conclusions obtained from the volumetric and acoustic studies. These parameters are helpful to study the structure nurturing, solvation behavior and various interactions present in the ternary solutions of (amino acid + [mim][Cl] + water). |
| Databáze: | OpenAIRE |
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