In situ hydrodeoxygenation upgrading of pine sawdust bio-oil to hydrocarbon biofuel using Pd/C catalyst
| Autor: | James Julson, Eric Boakye, Shouyun Cheng, Fletcher Corbin, Lin Wei, Mustafa Radhi Alsowij, Douglas E. Raynie |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Acid value Hydrogen 020209 energy Batch reactor chemistry.chemical_element 02 engineering and technology 021001 nanoscience & nanotechnology Catalysis Hydrocarbon chemistry Chemical engineering Biofuel 0202 electrical engineering electronic engineering information engineering Organic chemistry Heat of combustion 0210 nano-technology Hydrodeoxygenation |
| Zdroj: | Journal of the Energy Institute. 91:163-171 |
| ISSN: | 1743-9671 |
| Popis: | Hydrodeoxygenation (HDO) is effective for upgrading bio-oil to biofuel. However, the upgrading cost increased due to the high consumption of external hydrogen. In this paper, the hydrogen generated from cheap water using zinc hydrolysis for in situ bio-oil HDO was reported. The effect of different temperatures (200 °C, 250 °C and 300 °C) on bio-oil HDO over Pd/C catalyst was investigated in a batch reactor. The results show that 250 °C yielded biofuel with the highest heating value at 30.17 MJ/kg and the highest hydrocarbons content at 24.09%. Physicochemical properties including heating value, total acid number and chemical compositions of the produced biofuels improved significantly in comparison with that of the original bio-oil. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect