ChemInform Abstract: Concise Biomimetic Total Syntheses of Both Antipodes of Balasubramide

Autor:	Michael A. Kerr, Michael B. Johansen, Andrew B. Leduc
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Natural product chemistry Stereochemistry Intramolecular force Epoxide Antipodal point General Medicine Enantiomer Balasubramide
Zdroj:	ChemInform. 39
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200808200
Popis:	A two-step, protecting-group-free synthesis of the -natural product balasubramide, using an Yb(OTf) 3-catalyzed -intramolecular epoxide opening, is reported. Both enantiomers of the natural product are available from the antipodal forms of the starting epoxycinnamic acid.
Databáze:	OpenAIRE
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