Regularities of the formation of silver nanoparticles with oligostyrylcarboxylate ligands

Autor:	L. I. Kuzub, Ya. I. Estrin, Elmira R. Badamshina, A. A. Grishchuk, G. A. Estrina, L. L. Gur’eva
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Polymers and Plastics chemistry Inorganic chemistry Materials Chemistry Ceramics and Composites Molecule Infrared spectroscopy Photochemistry Micelle Triethylamine Silver nanoparticle
Zdroj:	Polymer Science Series B. 57:608-615
ISSN:	1555-6123 1560-0904
DOI:	10.1134/s1560090415060093
Popis:	Regularities of the formation of silver nanoparticles with oligostyrylcarboxylate ligands during the one-step reduction of silver oligostyrylcarboxylates with triethylamine are studied via UV–Vis and IR spectroscopy. It is shown that the synthesis of silver nanoparticles occurs in a system with micellar organized molecules of the oligomeric precursor–ionomer. The formation of silver nanoparticles occurs through the successive formation of a diphilic silver oligostyrylcarboxylate/triethylamine complex, reduction of Ag+ in the cores of reverse micelles with the formation of (Ag0)n nuclei, and their subsequent growth through self-assembly.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6b584fc81ef196b9c4ed3e001d7a5e1f https://doi.org/10.1134/s1560090415060093 Zobrazit plný text záznamu Full text from SpringerLink