Magnetic Pd@Fe3O4 composite nanostructure as recoverable catalyst for sonoelectrohybrid degradation of Ibuprofen
| Autor: | Jeehyeong Khim, Beomguk Park, Mingcan Cui, Pengpeng Qiu, Aniruddha B. Pandit, Binota Thokchom |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Acoustics and Ultrasonics chemistry.chemical_element 02 engineering and technology 010501 environmental sciences Electrochemistry 01 natural sciences Sonochemistry Catalysis law.invention Inorganic Chemistry Adsorption law Chemical Engineering (miscellaneous) Environmental Chemistry Radiology Nuclear Medicine and imaging 0105 earth and related environmental sciences Electrolysis Nanocomposite Organic Chemistry 021001 nanoscience & nanotechnology Chemical engineering chemistry Degradation (geology) 0210 nano-technology Palladium |
| Zdroj: | Ultrasonics Sonochemistry. 34:262-272 |
| ISSN: | 1350-4177 |
| DOI: | 10.1016/j.ultsonch.2016.05.030 |
| Popis: | In the present research, the degradation of an emerging pharmaceutical micro-pollutant, Ibuprofen (IBP) by using Pd@Fe3O4 and a hybrid sono-electrolytical (US/EC) treatment system has been demonstrated for the first time. The magnetically separable nanocomposite, Pd@Fe3O4 catalyst was synthesized following co-precipitation method to enhance the efficiency of US/EC system. The synthesized catalyst showed a strong reusable property even after applying for five times and in all the five cases, 100% degradation of IBP was maintained. It not only enhanced the IBP degradation rate, but also reduced the energy consumption of the system by ∼35%. Its strong magnetization value of 64.27emug-1 made it easily separable. Hence, a comprehensive knowledge on the application of combined energy based US/EC system and magnetically separable multifunctional catalysts for degradation of intractable pollutants like Ibuprofen was achieved, assuring that US/EC can be an effective option for IBP treatment. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect