Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction, Part I
| Autor: | Zahida Maqbool, Mashooda Hasan, Kevin T. Pott, Abdul Malik, Tanveer Ahmad Nizami, Wolfgang Voelter |
|---|---|
| Rok vydání: | 1997 |
| Předmět: | |
| Zdroj: | Zeitschrift für Naturforschung B. 52:1383-1392 |
| ISSN: | 1865-7117 0932-0776 |
| DOI: | 10.1515/znb-1997-1117 |
| Popis: | A convenient pathway to a variety of β-and α-C-nucleosides has been developed by utilizing 1,3-dipolar cycloaddition reactions of various exocyclic and endocyclic heterocyclic ylides with β (5a) and α (5b) anomers of ethyl 3-(2′,3′-O-isopropylidene-5′-O-trityl-D-ribofurano-syl) propiolate, respectively. Assignment of configuration at exposition of the C-nucleosides could be made by a comparative study of the properties of corresponding α and β anomers with a reasonable degree of certainity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|