| Popis: |
A new meso-tetraalkyl porphyrin manganese complex, 5,10,15,20-tetrakis(ethoxycarbonyl)porphyrinatomanganese (MnIIITECPCl), had been prepared and characterized by X-ray structure determination. MnIIITECPCl exists as a coordinated dimer in its crystal structure with a weak antiferromagnetic coupling between two Mn(III) ions. The catalytic oxidation of styrene by MnIIITECPCl was carried out in acetonitrile. MnIIITECPCl was found to be recyclable with a high conversion efficiency when using TBHP as an oxidant and the major product was benzaldehyde. MnIIITECPCl was also reusable by using an PhIO oxidant, but the major products turned out to be phenyl acetaldehyde and styrene epoxide. |
