Dimethyl Sulfoxide/Potassium Hydroxide: A Superbase for the Transition Metal-Free Preparation of Cross-Coupling Products

Autor:	Seok Hwan Kim, Isabelle Thome, Duanteng Chen, Astrid Beyer, Julien Bonnamour, Carsten Bolm, Sukbok Chang, Yu Yuan, Erik Zuidema
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Potassium hydroxide chemistry Nucleophile Dimethyl sulfoxide Aryl Potassium tert-butoxide Superbase Inorganic chemistry Polymer chemistry Halide General Chemistry Catalysis
Zdroj:	Advanced Synthesis & Catalysis. 352:2892-2898
ISSN:	1615-4150
DOI:	10.1002/adsc.201000575
Popis:	Potassium hydroxide (KOH) in dimethyl sulfoxide (DMSO) forms a superbasic medium that allows one to access cross-coupling products from reactions between aryl halides with various sulfur-, oxygen- and nitrogen-based nucleophiles under transition metal-free conditions.
Databáze:	OpenAIRE
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