| Popis: |
This review focuses on synthesis and properties of 1,3-phosphorus-containing zwitterions that have at the anionic center cyano-group and either ester (type one) or carbamate (type two) moieties. Zwitterions belonging to type one possess dual nucleophile reactivity, i.e., depending on the properties of the electrophiles they may form either C- or N-derivatives. Zwitterions belonging to type two possess triple nucleophile reactivity. In their reactions with electrophiles, they may form even three types of derivatives, i.e., at the C-, O- or N-atoms. This nucleophile multiplicity is not just interesting from the theoretical standpoint but may also open the ways to the synthesis of new compounds that can be important from the practical standpoint, such as physiologically active compounds, catalysts, analytical reagents, etc. |
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