1-Silacyclopent-3-en-1-ylidene, a cyclic silylene from the reactions of silicon atoms and a silicon atom synthon

Autor:	Yue Shen Chen, Peter P. Gaspar, Stanislaw Konieczny, Siu Hong Mo, Eric C. L. Ma, Adam P. Helfer
Rok vydání:	1981
Předmět:	Silicon Synthon Silylene chemistry.chemical_element General Chemistry Substrate (electronics) Photochemistry Biochemistry Chemical reaction Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Organic reaction Yield (chemistry) Atom
Zdroj:	Journal of the American Chemical Society. 103:7344-7345
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00414a055
Popis:	It is now possible, however, to generate 1-silacyclopent-3-en-1-ylidene (1) directly, and it reacts with butadiene to form in high yield a product which we have also found from recoiling silicon atoms and from the cocondensation of silicon vapor with the same substrate. This paper reports new evidence for the intermediacy of (1) in the reactions of silicon atoms, the first fruitful reaction of thermally evaporated silicon with a hydrocarbon, and a silicon atom synthon.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6ae52390b2b12f8e61922c8ffb75bce2 https://doi.org/10.1021/ja00414a055 Zobrazit plný text záznamu