ChemInform Abstract: Dichotomous Reaction Pathways for the Oxidative Palladium(II)-Catalyzed Intramolecular Acyloxylation of Alkenes

Autor:	Mélanie M. Lorion, Julie Oble, Fadila Louafi, Giovanni Poli
Rok vydání:	2016
Předmět:	chemistry.chemical_classification Olefin fiber Allylic rearrangement Carboxylic acid food and beverages chemistry.chemical_element General Medicine Medicinal chemistry Catalysis chemistry Intramolecular force Moiety Amination Palladium
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201607192
Popis:	This work provides an in-depth investigation of the Pd(II)-catalyzed oxidative cyclization of various alkenoic acids bearing different tethers between the carboxylic acid moiety and the olefin function, showcasing how different mechanistic pathways (oxypalladation or allylic C–H activation) can be operative. The factors biasing toward one or the other of these reactivities are rationally discussed and compared with our recent studies on the Pd(II)-catalyzed intramolecular amination.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6ad29ac1d026d0318dd74455c3f81b0b https://doi.org/10.1002/chin.201607192 Zobrazit plný text záznamu Plný text