New Synthetic Routes to Biologically Interesting Geranylated Acetophenones from Melicope Semecarpifolia and Their Unnatural Prenylated and Farnesylated Derivatives

Autor:	Likai Xia, Jae-Jin Shim, Xin Li, Yong Rok Lee, Manchala Narasimhulu
Rok vydání:	2010
Předmět:	Chalcone chemistry.chemical_compound Prenylation Chemistry Stereochemistry Melicope semecarpifolia Organic chemistry General Chemistry
Zdroj:	Bulletin of the Korean Chemical Society. 31:664-669
ISSN:	0253-2964
DOI:	10.5012/bkcs.2010.31.03.664
Popis:	This paper describes a new synthetic approach for biologically interesting geranylated acetophenones. The first total syn- theses of 1-(5-geranyloxy-7-hydroxy-2,2-dimethyl-2H-chromen-8-yl)ethanone and 1-(5-geranyloxy-7-hydroxy-2- methyl-2-(4-methylpent-3-enyl)-2H-chromen-8-yl)ethanone, isolated from Melicope semecarpifolia, were carried out starting from commercially available 2,4,6-trihydroxyacetophenone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6ab2245e93e6905973231cb5b84e3522 https://doi.org/10.5012/bkcs.2010.31.03.664 Zobrazit plný text záznamu