Coordination properties of N-(Thio)phosphorylated thioureas and thioamides with respect to Co(II), Ni(II), Zn(II), and Cd(II) ions in solution

Autor:	M. S. Starikova, N. G. Zabirov, F. D. Sokolov, Yu. I. Sal'nikov, Marianna P. Kutyreva, V. V. Brus’ko, N. A. Ulakhovich
Rok vydání:	2007
Předmět:	Chemistry Materials Science (miscellaneous) Metal ions in aqueous solution Organic solvent Inorganic chemistry Thio Mass spectrometry Ion Inorganic Chemistry chemistry.chemical_compound Thiourea Stability constants of complexes Physical and Theoretical Chemistry Nuclear chemistry
Zdroj:	Russian Journal of Inorganic Chemistry. 52:1050-1055
ISSN:	1531-8613 0036-0236
DOI:	10.1134/s0036023607070133
Popis:	The acid-base and coordination properties of N-(thio)phosphorylated thioureas and thioamides R1C(X)NHP(Y)R 2 2 , where X, Y = S, O (in various combinations); R1 = t−Bu, i-Pr, PhNH, Ph; R2 = (OPr−i), with respect to Co(II), Ni(II), Zn(II), and Cd(II) ions have been studied by pH-metry and UV spectrometry in an organic solvent. The pK values, the stability constants logβ and the maximum accumulated fractions of complex species in the solution have been calculated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6a93b3e79f060eca7e5cbbe3f791064d https://doi.org/10.1134/s0036023607070133 Zobrazit plný text záznamu Full text from SpringerLink