ChemInform Abstract: Claisen and Fries Rearrangement Studies of Some Naphthalene Derivatives

Autor: Shawlene Nefdt, Ivan R. Green, Victor I. Hugo, Petra W. Snijman
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 26
ISSN: 0931-7597
Popis: Comparative Claisen rearrangements of 4-hydroxy - (7) and 4-acetoxy-1-allyloxy-5,8-ethano-5,8-dihydro-5-methoxynaphthalene (1) leading after chemoselective methylation to 4-acetoxy-2-allyl-1,5-dimethoxy-naphthalene (9) were investigated. Lewis acid mediated Fries rearrangements of 4-acetoxy-2-allyl-alkoxy-5-ethoxynaphthalenes lead to the formation of a naphtho[1,2 - b]furan in one case only.
Databáze: OpenAIRE