ChemInform Abstract: Claisen and Fries Rearrangement Studies of Some Naphthalene Derivatives
Autor: | Shawlene Nefdt, Ivan R. Green, Victor I. Hugo, Petra W. Snijman |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 26 |
ISSN: | 0931-7597 |
Popis: | Comparative Claisen rearrangements of 4-hydroxy - (7) and 4-acetoxy-1-allyloxy-5,8-ethano-5,8-dihydro-5-methoxynaphthalene (1) leading after chemoselective methylation to 4-acetoxy-2-allyl-1,5-dimethoxy-naphthalene (9) were investigated. Lewis acid mediated Fries rearrangements of 4-acetoxy-2-allyl-alkoxy-5-ethoxynaphthalenes lead to the formation of a naphtho[1,2 - b]furan in one case only. |
Databáze: | OpenAIRE |
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