Synthesis Characterization, Crystal Structure, and Fluorescence of a New Samarium Schiff Base Complex
| Autor: | Murad A. AlDamen, Mutasem Omar Sinnokrot, Hassan K. Juwhari, Mahmoud Salman, I. Sarairah, Mohammad S. Mubarak, Abdel Aziz Abu-Yamin, Jibril Al-Hawarin |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Photoluminescence Schiff base chemistry.chemical_element 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry Samarium chemistry.chemical_compound Crystallography chemistry Materials Chemistry Molecule Orthorhombic crystal system Physical and Theoretical Chemistry 0210 nano-technology Spectroscopy Single crystal |
| Zdroj: | Journal of Structural Chemistry. 59:1935-1943 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s0022476618080243 |
| Popis: | A new samarium Schiff base complex with the formula [SmIII(NO3)3(H2O)L2].EtOH, where L = {(E)-2- (((4-(ethoxycarbonyl)phenyl)iminio)-methyl)phenolate}, is synthesized. Its molecular structure is determined by means of single crystal X-ray diffraction (XRD). The complex crystallizes in the orthorhombic space group Pbca with the following unit cell dimensions: a = 14.1304(19) A, b = 18.0218(13) A, and c = 31.246(2) A. Photoluminescence characteristics of the complex are investigated experimentally in the solid state and obtained theoretically using the Sparkle/PM7 modeling. Moreover, several methods such as powder XRD, FT-IR and UV-Visible spectroscopy are utilized to confirm the structure of the complex. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|