| Autor: |
Yue-Jin Liu, Cui-Hong Chen, Zheng-Xin Zhou, Wei-Hao Rao, Bin Liu, Yun Chai, Ming-Hua Zeng, Li Liu, Ran Xu |
| Rok vydání: |
2019 |
| Předmět: |
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| Zdroj: |
Organic Chemistry Frontiers. 6:442-446 |
| ISSN: |
2052-4129 |
| DOI: |
10.1039/c8qo01215f |
| Popis: |
Ligand-promoted room-temperature Pd(II)-catalyzed direct C–H alkynylation of phenylacetic amides has been developed using commercially available TIPS-acetylene as an efficient alkynylating reagent, where 8-aminoquinoline was employed as a removable bidentate auxiliary, thus giving rise to optically pure ortho-alkynylated α-APA in a highly efficient manner. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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