PREPARATION OF TEMPO-CELLULOSE NANOFIBER/ZINC OXIDE AS ANTIMICROBIAL AND METHYLENE BLUE PHOTO-DEGRADING NANOCOMPOSITE

Autor: Hazem Hassan, Ahmed K. El-Ziaty, Mohamed El-Sakhawy, Ahmed Salama
Rok vydání: 2021
Předmět:
Zdroj: Cellulose Chemistry and Technology. 55:365-373
ISSN: 2457-9459
0576-9787
Popis: "Photo-catalytic degradation of organic dyes in aquatic environments under visible light irradiation affords an efficient and economic technique for environmental remediation. TEMPO-oxidized cellulose nanofibers/zinc oxide nanocomposite (TEMPO-CNF/ZnO) was prepared through oxidation of cellulose pulp, followed by zinc oxide precipitation in the presence of oxidized fibers. TEMPO-CNF/ZnO was characterized by different techniques. The degradation rate of methylene blue (MB) by TEMPO-CNF/ZnO was gradually increased with increasing pH and the degradation reached 86% within 340 minutes at pH 7. The kinetic study showed that the pseudo-first-order kinetic best fitted the photo-catalytic process. A mechanism was proposed for the degradation of MB using TEMPO-CNF/ZnO under visible light irradiation. TEMPO-CNF/ZnO showed high antibacterial activity against S. aureus and E. coli. Thus, the TEMPO-CNF/ZnO nanocomposite has been demonstrated to be an effective photo-catalytic material for degrading MB under visible light irradiation."
Databáze: OpenAIRE