Synthesis and structure of organotin complexes of ytterbium
| Autor: | Sergey F. Ziltsov, Leonid N. Bochkarev, Lev N. Zakharov, Oleg V. Grachev, Yury T. Struchkov |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Ytterbium biology Dimer Organic Chemistry Inorganic chemistry Ionic bonding chemistry.chemical_element Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Covalent bond Yield (chemistry) Materials Chemistry biology.protein Physical and Theoretical Chemistry Tin Inorganic compound Organic anion |
| Zdroj: | Journal of Organometallic Chemistry. 436:299-311 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(92)85062-2 |
| Popis: | Reactions of Ph 3 SnCl, PhSnCl 3 and Ph 3 SnSnPh 3 with ytterbium in THF lead to the formation of the complex (Ph 3 Sn 2 Yb(THF) 4 ( 1 * in high yields. According to X-ray data, tin atoms in complex 1 are covalently bonded with the ytterbium atom. Ionic organotin complex of ytterbium [(Ph 3 Sn 3 Sn] − 2 [Yb 2 Cl 2 (DME) 6 ] 2+ ( 2 was synthesised in 75% yield by the reaction of Ph 2 SnCl 2 with ytterbium. According to X-ray analysis, the compound consists of [(Ph 3 Sn 3 Sn] − anions and dimeric ytterbium cations with μ 2 -bridged chlorine atoms [(DME) 3 YbClYb(DME 3 ] 2+ . |
| Databáze: | OpenAIRE |
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