Substituted polyacetylenes through the ring-opening metathesis polymerization (ROMP) of substituted cyclooctatetraenes: A route into soluble polyacetylene
| Autor: | Jeffrey S. Moore, Robert H. Grubbs, Nathan S. Lewis, Eric J. Ginsburg, T. H. Jozefiak, Seth R. Marder, Joseph W. Perry, Michael J. Sailor, Christopher B. Gorman |
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| Rok vydání: | 1991 |
| Předmět: |
Chemistry
Mechanical Engineering Metals and Alloys macromolecular substances ROMP Conjugated system Condensed Matter Physics Metathesis Electronic Optical and Magnetic Materials Polyacetylene chemistry.chemical_compound Polymerization Mechanics of Materials Polymer chemistry Materials Chemistry Ring-opening metathesis polymerisation Organic chemistry Pendant group Acyclic diene metathesis |
| Zdroj: | Synthetic Metals. 41:1033-1038 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/0379-6779(91)91550-t |
| Popis: | Ring-Opening metathesis polymerization (ROMP) of substituted cyclooctatetraenes (COT) produces polyacetylenes that are substituted, on the average, every eight carbon atoms. In several cases these polymers are soluble and highly conjugated. The effect of the side group on the optical, electrical and materials properties of the polymer will be discussed. |
| Databáze: | OpenAIRE |
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