Regioselective and Chemoselective Reduction of α,β-Unsaturated Carbonyl Compounds by NaBH4/Ba(OAc)2 as a Reducing System

Autor:	Behrooz Khezri, Mina Mohamadi, Davood Setamdideh
Rok vydání:	2013
Předmět:	Reduction (complexity) Allylic rearrangement Chemistry Regioselectivity Medicinal chemistry
Zdroj:	Organic Chemistry International. 2013:1-5
ISSN:	2090-2018 2090-200X
DOI:	10.1155/2013/127585
Popis:	α,β-unsaturated aldehydes and ketones are regioselectively reduced to the corresponding allylic alcohols with NaBH4/Ba(OAc)2 system in CH3CN. This system is also efficient for the chemoselective reduction of enals in the presence of enones at room temperature.
Databáze:	OpenAIRE
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