Alkyl complexes of divalent lanthanides and heavy alkaline earth metals

Autor:	Dmitry O. Khristolyubov, Alexander A. Trifonov, Dmitry M. Lyubov
Rok vydání:	2021
Předmět:	chemistry.chemical_classification Lanthanide Alkaline earth metal chemistry Inorganic chemistry General Chemistry Alkyl Divalent
Zdroj:	Russian Chemical Reviews. 90:529-565
ISSN:	1468-4837 0036-021X
DOI:	10.1070/rcr4992
Popis:	The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The synthetic aspects and structural features of this unique class of organometallic compounds, which contain highly reactive M–C bonds, including alkyl, α-silylmethyl, and also benzyl, diphenylmethyl, and triphenylmethyl derivatives are considered. The bibliography includes 157 references.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6a033c00d0c386f34b3d2161e93daf20 https://doi.org/10.1070/rcr4992 Zobrazit plný text záznamu