Adamanthylazoles: VII. Acid-catalyzed Adamanthylation of C-C- and C-N-Linked Azopyrazoles
Autor: | N. E. Kuz'mina, V. V. Kachala, E. L. Golod, A. S. Gavrilov |
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Rok vydání: | 2004 |
Předmět: | |
Zdroj: | Russian Journal of General Chemistry. 74:752-762 |
ISSN: | 1070-3632 |
Popis: | Acid-catalyzed N-adamanthylation of C-C-linked pyrazolyl- and tetrazolylpyrazoles in H3PO4- AcOH (4:1) or H2SO4 involves, depending on conditions, one or both rings. The mutual effect of the rings is weak. C-N-Linked azolylpyrazoles are a conjugated system, and the formation of N-adamanthyl derivatives is strongly affected by the second azolyl ring. |
Databáze: | OpenAIRE |
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