Adamanthylazoles: VII. Acid-catalyzed Adamanthylation of C-C- and C-N-Linked Azopyrazoles

Autor: N. E. Kuz'mina, V. V. Kachala, E. L. Golod, A. S. Gavrilov
Rok vydání: 2004
Předmět:
Zdroj: Russian Journal of General Chemistry. 74:752-762
ISSN: 1070-3632
Popis: Acid-catalyzed N-adamanthylation of C-C-linked pyrazolyl- and tetrazolylpyrazoles in H3PO4- AcOH (4:1) or H2SO4 involves, depending on conditions, one or both rings. The mutual effect of the rings is weak. C-N-Linked azolylpyrazoles are a conjugated system, and the formation of N-adamanthyl derivatives is strongly affected by the second azolyl ring.
Databáze: OpenAIRE