Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6‐Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)

Autor:	Svea Jelonek, Reinhard Kirmse, Andreas Voigt, Reinhard Felsberg, Evamarie Hey-Hawkins, Thomas Gelbrich, Steffen Blsurock
Rok vydání:	1997
Předmět:	Inorganic Chemistry Crystallography Coordination sphere law Chemistry Molybdenum Inorganic chemistry chemistry.chemical_element Crystal structure Electron paramagnetic resonance law.invention
Zdroj:	Chemische Berichte. 130:807-812
ISSN:	0009-2940
DOI:	10.1002/cber.19971300621
Popis:	[Cp′MoCl4(CH3CN) (Cp′=C5H4Me) react with 2,4,6-triisopropylphenylphosphane or cyclohexylphosphane to give the phosphane complexes [Cp′MoCl4(PH2R)] [R=2,4,6-Pri3C6H2 (1)]. 1 and 2, were characterized spectroscopically (IR, MS) and by crystal structure determinations. EPR investigations in liquid and frozen solution confirmed the presence of Mo(V) species and the data were used to analyze the spin-density distribution in the first coordination sphere.
Databáze:	OpenAIRE
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