A new P-chiral bisphosphine, 1,1′-bis[(t-butyl)methyl-phosphino]ferrocene, as an effective ligand in catalytic asymmetric hydrosilylation of simple ketones

Autor:	Tsuneo Imamoto, Hideyuki Tsuruta
Rok vydání:	1999
Předmět:	Chemistry Hydrosilylation Ligand Organic Chemistry chemistry.chemical_element Optically active Medicinal chemistry Catalysis Rhodium Inorganic Chemistry chemistry.chemical_compound Ferrocene Organic chemistry Physical and Theoretical Chemistry Enantiomer
Zdroj:	Tetrahedron: Asymmetry. 10:877-882
ISSN:	0957-4166
DOI:	10.1016/s0957-4166(99)00042-7
Popis:	The asymmetric hydrosilylation of simple ketones was catalyzed by a rhodium complex with a P-chiral bisphosphine, 1,1′-bis[(t-butyl)methylphosphino]ferrocene, to give optically active alcohols with enantiomeric excesses of up to 92%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::698b09f04ad79ea01c5439e24910194c https://doi.org/10.1016/s0957-4166(99)00042-7 Zobrazit plný text záznamu Full Text from ScienceDirect