Claisen Orthoester Rearrangement Reaction with Secondary and Tertiary Allylic Alcohols: Synthesis of 1,2 Secochrysanthemates and Their Structural Analogues

Autor:	G. H. Kulkarni, G. S. Joshi, A. A. Arbale, S. V. Kelkar
Rok vydání:	1990
Předmět:	chemistry.chemical_compound Allylic rearrangement chemistry Biological property Organic Chemistry Organic chemistry Rearrangement reaction Orthoester Sigmatropic reaction Carroll rearrangement
Zdroj:	Synthetic Communications. 20:839-847
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919008052329
Popis:	A simple route is described for the synthesis of 1,2 Seco-chrysanthemic acid and their structural analogues, employing Claisen orthoester rearrangement reaction in the key-step of synthesis. These acids have been prepared with a view to evaluating some of the esters prepared from them for possible insecticidal and other biological properties.
Databáze:	OpenAIRE
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