Alternative Metal-Free Synthesis of Diorganoyl Selenides and Tellurides Mediated by Oxone®

Autor:	Márcio S. Silva, Diego Alves, José S. S. Neto, Gelson Perin, Luis Fernando B. Duarte
Rok vydání:	2018
Předmět:	Green chemistry Steric effects 010405 organic chemistry Chemistry Aryl Organic Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Solvent chemistry.chemical_compound Organoselenium Compound Metal free
Zdroj:	Synlett. 29:1479-1484
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0036-1591992
Popis:	We herein describe an alternative metal-free methodology for the synthesis of diorganyl selenides and tellurides mediated by ­Oxone®. The products were obtained in moderate to excellent yields by reactions of diorganyl diselenides or ditellurides with aryl boronic acids mediated by Oxone® with use of EtOH as the solvent. The methodology is applicable to a broad scope of diorganyl dichalcogenides and aryl boronic acids containing electron-rich, electron-poor, and sterically hindered substituents.
Databáze:	OpenAIRE
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