Analysis of zinc dialkyl dithiophosphates by nonaqueous capillary electrophoresis and application to lubricants

Autor: Keith D. Bartle, K. A. Mccormack, D. J. Abbott, V. R. A. Thibon
Rok vydání: 1999
Předmět:
Zdroj: Journal of Microcolumn Separations. 11:71-80
ISSN: 1520-667X
1040-7685
DOI: 10.1002/(sici)1520-667x(1999)11:1<71::aid-mcs9>3.0.co;2-z
Popis: Capillary electrophoresis has been successfully applied to the separation of four different commercial zinc dialkyldithiophosphate (ZDDP) mixtures and to the analysis of the ZDDP in fresh and used lubricating oils. Nonaqueous systems composed of methanol, tetrahydrofuran, and acetonitrile with tetraethylammonium, tetramethylammonium, or ammonium hydroxide and acetic acid as buffer additives were employed to separate the metal complexes according to the different hydrocarbon chain lengths and structures of the alkyl substituents. ©1999 John Wiley & Sons, Inc. J Micro Sep 11: 71–80, 1999
Databáze: OpenAIRE