A new synthesis of methyl-isopelletierine: Experiments on the synthesis of alkaloids of punica granatum 4th communication

Autor: C. C. Kloppenburg, J. P. Wibaut
Rok vydání: 2010
Předmět:
Zdroj: Recueil des Travaux Chimiques des Pays-Bas. 65:100-104
ISSN: 0165-0513
DOI: 10.1002/recl.19460650205
Popis: By the action of dimethyl sulphate on 1-(2-pyridyl)-propanone-2 the corresponding quaternary N-methylpyridinium salt is prepared; by partial hydrogenation of this compound we obtained 1-(α-N-methylpiperidyl)-propanone-2 or methylisopelletierine in a yield of 47% of the theoretical calculated on α-picolylmethylketone.
Databáze: OpenAIRE