cis-Dichloro(di-tert-butylphosphine-κP)(triphenylphosphine-κP)platinum(II) tetrahydrofuran hemisolvate
Autor: | Andrzej Robaszkiewicz, Elke Baum, Jarosław Chojnacki, Jerzy Pikies, Eberhard Matern |
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Rok vydání: | 2007 |
Předmět: |
Tert butyl
biology chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy Condensed Matter Physics biology.organism_classification Photochemistry Chloride Medicinal chemistry chemistry.chemical_compound chemistry Furan medicine Tetra General Materials Science Platinum Phosphine medicine.drug |
Zdroj: | Acta Crystallographica Section E Structure Reports Online. 63:m680-m682 |
ISSN: | 1600-5368 |
DOI: | 10.1107/s1600536807005259 |
Popis: | The title compound, [PtCl2(C8H19P)(C18H15P)]·0.5C4H8O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-tert-butyl-2-trimethylsilyltriphosphine. The 31P{1H} NMR spectrum of the reaction mixture shows the formation of the title compound together with a significant amount of triphenylphosphine and 1,1,3,3-tetra-tert-butyltriphosphine. |
Databáze: | OpenAIRE |
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