Hydrocarbon group-type separations for high aromatic fuels by supercritical fluid chromatography on packed capillary columns
| Autor: | Anthony A. Clifford, Shahidah Mohd Shariff, Peter Myers, Mark M. Robson, Keith D. Bartle |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
chemistry.chemical_classification
Chromatography Capillary action Chemistry General Chemical Engineering Organic Chemistry Analytical chemistry Supercritical fluid extraction Energy Engineering and Power Technology Fluorescence Supercritical fluid chemistry.chemical_compound Fuel Technology Hydrocarbon Phase (matter) Carbon dioxide Supercritical fluid chromatography |
| Zdroj: | Fuel. 77:927-931 |
| ISSN: | 0016-2361 |
| DOI: | 10.1016/s0016-2361(97)00293-7 |
| Popis: | The contents of total aromatics and of mono-, di-, and polyaromatics in fuels may be rapidly and conveniently determined by supercritical fluid chromatography on capillary columns packed with silica using a supercritical carrier. The use of carbon dioxide mobile phase permits detection by flame ionisation. A study of the retention behaviour of test compounds allowed the separation temperature and pressure to be optimised. The aromatic content of a range of fuels (17–88%) determined in this way was in good agreement with fluorescent indicator analysis. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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