Total Synthesis of (+)-Brefeldin C Utilizing Aza-Claisen Rearrangement

Autor:	Hiroaki Abe, Hiroto Kaku, Makoto Inai, Keiko Tominaga, Tomoyuki Esumi, Tetsuto Tsunoda, Mitsuyo Horikawa, Shingo Mukoujima, Takeshi Nishii
Rok vydání:	2011
Předmět:	Claisen rearrangement Chemistry Stereochemistry Kornblum–DeLaMare rearrangement Brefeldin C Organic Chemistry Total synthesis Sigmatropic reaction Carroll rearrangement Stereocenter
Zdroj:	Synlett. 2011:1459-1461
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0030-1260762
Popis:	The total synthesis of (+)-brefeldin C was accomplished. Anasymmetric aza-Claisen rearrangement developed by our laboratorywas employed to construct the C-4 and C-5 stereogenic centers of(+)-brefeldin C as a key step.
Databáze:	OpenAIRE
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