Azeotropic phenomena in a dilute solution of lithium hydride in lithium at liquid-vapor phase equilibrium

Autor: K. A. Yakimovich
Rok vydání: 2010
Předmět:
Zdroj: Russian Journal of Physical Chemistry A. 84:1154-1157
ISSN: 1531-863X
0036-0244
DOI: 10.1134/s0036024410070137
Popis: A Li-LiH-type system under liquid-vapor phase equilibrium conditions was considered. Liquid is a binary infinitely dilute solution of lithium hydride in lithium, and the coexisting vapor phase is a multi-component chemically reacting ideal mixture of gas components. The phenomenon of the existence of azeotropy in such systems, earlier unknown, was established. The concentration of the components was expressed in the atomic fractions of hydrogen in both phases. The temperature and concentration boundaries of the azeotropic zone were found. The trends revealed are of importance for applications.
Databáze: OpenAIRE