Exploration into the (CH)4 hydrocarbon manifold - thermal stabilization pathway of rac-tritwistatriene

Autor:	Dieter Hunkler, Thomas Otten, Hermann Müller-Bötticher, Horst Prinzbach, Hans Fritz
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Organic Chemistry Sous vide Thermal decomposition Biochemistry Cycloaddition law.invention Hydrocarbon chemistry law Computational chemistry Drug Discovery Thermal Manifold (fluid mechanics)
Zdroj:	Tetrahedron Letters. 33:4153-4156
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)74676-4
Popis:	The preparative potential of rac -tritwistatriene ( 2 ) as precursor for other novel (CH) 14 hydrocarbons is explored. Solution thermolysis generates the primarily desired pentaene 1 together with trienes 7 and 9 . From FVP experiments, 1 is obtained together with triene 9 and pentaene 11 as thermodynamically more stable (CH) 14 isomers. The behavior of 1 in cycloaddition reactions is provisionally explored.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::68dfa9adbce0fb2951ec70f237d3030e https://doi.org/10.1016/s0040-4039(00)74676-4 Zobrazit plný text záznamu