ChemInform Abstract: Double Decarboxylative Claisen Rearrangement Reactions: Microwave-Assisted de novo Synthesis of Pyridines

Autor: Stephen C. Smith, Donald Craig, Federica Paina
Rok vydání: 2008
Předmět:
Zdroj: ChemInform. 39
ISSN: 1522-2667
0931-7597
Popis: Microwave-assisted double decarboxylative Claisen rearrangement of bis(allyl) 2-tosylmalonates provides substituted 1,6-heptadienes, which may be alkylated, and then converted into pyridines by ozonolysis followed by reaction with ammonia generated in situ under microwave conditions.
Databáze: OpenAIRE