ChemInform Abstract: Double Decarboxylative Claisen Rearrangement Reactions: Microwave-Assisted de novo Synthesis of Pyridines
Autor: | Stephen C. Smith, Donald Craig, Federica Paina |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | ChemInform. 39 |
ISSN: | 1522-2667 0931-7597 |
Popis: | Microwave-assisted double decarboxylative Claisen rearrangement of bis(allyl) 2-tosylmalonates provides substituted 1,6-heptadienes, which may be alkylated, and then converted into pyridines by ozonolysis followed by reaction with ammonia generated in situ under microwave conditions. |
Databáze: | OpenAIRE |
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