Benzene hydrogenation over polydopamine-modified MCM-41 supported Ruthenium-Lanthanum catalyst

Autor:	Meidong Liang, Xuanyan Liu, Hongguang Liao, Yanjuan Xiao, Hongmei Zhong, Xiaoguang Yu, Haoyan He
Rok vydání:	2018
Předmět:	Cyclohexene chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Ruthenium Inorganic Chemistry chemistry.chemical_compound Adsorption chemistry Polymerization MCM-41 Polymer chemistry Physical and Theoretical Chemistry 0210 nano-technology Mesoporous material Benzene
Zdroj:	Inorganic and Nano-Metal Chemistry. 48:599-606
ISSN:	2470-1564 2470-1556
DOI:	10.1080/24701556.2019.1567539
Popis:	Polydopamine–modified MCM-41 was prepared by sodium periodate–induced polymerization. Ru–La supported on MCM-41 and polydopamine–modified MCM-41 catalysts were prepared by double solvent impregnation method and tested for benzene hydrogenation to cyclohexene. Polydopamine–modified MCM-41 supported Ru–La catalyst exhibits much higher hydrophilicity and more moderate catalytic activity than unmodified MCM-41 supported Ru–La catalyst. The higher hydrophilicity, more moderate catalytic activity, and long-range order of mesoporous structure are beneficial for improving cyclohexene selectivity on account of the promotion of the desorption and the inhibition of the adsorption of cyclohexene. 47.0% of cyclohexene yield was obtained over Ru–La supported on polydopamine–modified MCM-41 in benzene hydrogenation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::68969f0ffca6221abf385bfb30fb5059 https://doi.org/10.1080/24701556.2019.1567539 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.