Photoinduced Hole and Electron Transfer from Poly(phenylene Vinylene) into Molecularly Doped Polymers

Autor: M. Stolka, Bing R. Hsieh, Samson A. Jenekhe, M. A. Abkowitz, J. S. Facci, Homer Antoniadis
Rok vydání: 1994
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 252:1-10
ISSN: 1058-725X
DOI: 10.1080/10587259408038205
Popis: Photoinduced hole transfer between photoexcited π-conjugated polymer, poly(p-phenylene vinylene) (PPV) and an adjacent trap-free hole-transport molecularly doped polymer containing TPD in a polycarbonate binder in an electric field, is analyzed. Also analyzed and described, under similar electric field conditions, is photoinduced electron transfer between PPV and a trap-free electron transport polymer containing BCFM and a polycarbonate binder. Transfer of carriers, both holes and electrons, to the respective transport layers is fast and coherent, without delay. The collection efficiency at an electric field of 4 × 105Vcm−1 is 25% for photoinduced holes and near 0.2% for photoinduced electrons.
Databáze: OpenAIRE