Computer-determined kinetic parameters from TG curves. Part XIII

Autor:	L.Z. Pollara, Salvatore S. Stivala, Leo Reich
Rok vydání:	1985
Předmět:	chemistry.chemical_compound Order of reaction Chemistry Siloxane Thermodynamics Activation energy Physical and Theoretical Chemistry Condensed Matter Physics Kinetic energy Instrumentation
Zdroj:	Thermochimica Acta. 90:189-193
ISSN:	0040-6031
DOI:	10.1016/0040-6031(85)87096-9
Popis:	Several procedures have been previously reported whereby non-isothermal TG (NITG) data can be analyzed for values of the activation energy ( E ) independent of values of the reaction order ( n ). In this paper, other expressions will be derived for the estimation of E which are essentially independent of n -values and are valid at relatively low degrees of conversion. These equations are applied to NITG data for a siloxane and teflon, as well as for theoretical data. The resulting computer and graphical procedures are both utilized to estimate E -values. Limitations of the methods are also mentioned.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::688034fd76e65ed0decc67760a4aa2e8 https://doi.org/10.1016/0040-6031(85)87096-9 Zobrazit plný text záznamu