Molecular architecture and conformation of macromolecules of novel polysilanes

Autor: N. V. Pertsova, Inga A. Ronova, I. I. Tverdokhlebova, V. M. Men'shov
Rok vydání: 1998
Předmět:
Zdroj: Russian Chemical Bulletin. 47:2348-2351
ISSN: 1573-9171
1066-5285
DOI: 10.1007/bf02641532
Popis: Molecular-weight parameters of new silane homo- and copolymers were analyzed. For all polymers, theMw values are close ((6.0–8.6)·104), the curves of molecular weight distribution are unimodal, andMw/Mn=2−2.5. Cyclic fragments or those containing the −C=C− groups make the major contribution to the polysilane chain rigidity.
Databáze: OpenAIRE