Thio-analogues of 2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones, synthesis and formation of metal complexes

Autor:	Katherine Buggle, Michael Nangle, Joseph Power, William K. Glass
Rok vydání:	1982
Předmět:	Metal chemistry.chemical_compound chemistry Transition metal visual_art visual_art.visual_art_medium Thio Organic chemistry General Chemistry Indene Hydrogen sulphide
Zdroj:	Monatshefte für Chemie - Chemical Monthly. 113:81-90
ISSN:	1434-4475 0026-9247
DOI:	10.1007/bf00814340
Popis:	2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones were converted into anils and dianils and then into monothio- and dithio-derivatives by treatment with hydrogen sulphide. The 2-pyridinyl monothioderivate was converted into S-alkyl ethers. In contrast with the dione1 the thio-derivatives readily formed isolable complexes with transition metals. Spectroscopic and magnetic data are reported.
Databáze:	OpenAIRE
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