Nitrosochlorination reaction of substituted imidazolin-2-ones

Autor:	A. I. Statsenskaya, Yu. G. Putsykin, Yu. A. Baskakov, V. V. Golovko
Rok vydání:	1986
Předmět:	Solvent Dry media reaction chemistry.chemical_compound chemistry Organic Chemistry Organic chemistry Nitrosyl chloride Alcohol Methanol
Zdroj:	Chemistry of Heterocyclic Compounds. 22:1084-1087
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00473483
Popis:	Interaction of nitrosyl chloride with 1-arylimidazolin-2-ones in methanol leads to the formation of 4,5-dimethyoxyimidazolidin-2-ones. Under similar conditions 1,5-diarylimidazolin-2-ones give 1,5-diaryl-4-oximino-5-alkoxyimidazolidin-2-ones. When the reaction is carried out in an aprotic solvent 1,5-diaryl-4-nitrosoimidazolin-2-ones are separated, and when treated with alcohol they give the final reaction products. An increase in temperature and duration of the reaction results in the formation of 1,5-diaryl-5-hydroxyhydantoins.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::680ea59f98e70dc0fc02f8ff42cf375f https://doi.org/10.1007/bf00473483 Zobrazit plný text záznamu Full text from SpringerLink