Long-Lived Mixed 2MLCT/MC States in Antiferromagnetically Coupled d3 Vanadium(II) Bipyridine and Phenanthroline Complexes

Autor: Ryan D. Dill, Anthony K. Rappé, Samuel G. Shepard, Matthew P. Shores, Niels H. Damrauer, Romeo I. Portillo
Rok vydání: 2020
Předmět:
Zdroj: Inorganic Chemistry. 59:14706-14715
ISSN: 1520-510X
0020-1669
DOI: 10.1021/acs.inorgchem.0c01950
Popis: Exploration of [V(bpy)3]2+ and [V(phen)3]2+ (bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline) using electronic spectroscopy reveals an ultrafast excited-state decay process and implicates a pair ...
Databáze: OpenAIRE