Long-Lived Mixed 2MLCT/MC States in Antiferromagnetically Coupled d3 Vanadium(II) Bipyridine and Phenanthroline Complexes
Autor: | Ryan D. Dill, Anthony K. Rappé, Samuel G. Shepard, Matthew P. Shores, Niels H. Damrauer, Romeo I. Portillo |
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Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 59:14706-14715 |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/acs.inorgchem.0c01950 |
Popis: | Exploration of [V(bpy)3]2+ and [V(phen)3]2+ (bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline) using electronic spectroscopy reveals an ultrafast excited-state decay process and implicates a pair ... |
Databáze: | OpenAIRE |
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