A Discrete Cobalt Complex Obtained from a 1 D Coordination Polymer for Highly Selective Sensing of the Mercury(II) Ion

Autor: Jae-Ho Jo, Anurag Mishra, Hyunuk Kim, Sangkook Woo, Ki-Whan Chi
Rok vydání: 2014
Předmět:
Zdroj: ChemPlusChem. 79:925-928
ISSN: 2192-6506
DOI: 10.1002/cplu.201402059
Popis: A unique structural transformation in a 1 D chain coordination network 2 is converted to a discrete compound 3 accompanied by a change in the ion-exchange system. Remarkably, 3 produced a turn-on fluorescence and selective sensing for Hg2+, whereas other ions, such as K+, Mg2+, Ca2+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+, and Cd2+, did not show any notable effects. Thus, the Hg2+-selective fluorescent chemosensor was free from interference by competing metal ions.
Databáze: OpenAIRE
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