Synthesis and Fluorescent Properties of Tetra-Biphenyl N -Substituted Phthalimides
| Autor: | Yu-Wei Shih, Lin Yan-Liang, Te-Fang Yang, Sheng-Han Huang |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Biphenyl
Phthalimides Quenching (fluorescence) biology Chemical structure 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology biology.organism_classification Photochemistry 01 natural sciences Fluorescence Medicinal chemistry 0104 chemical sciences Phthalimide chemistry.chemical_compound chemistry Tetra 0210 nano-technology Single crystal |
| Zdroj: | Journal of the Chinese Chemical Society. 64:1190-1196 |
| ISSN: | 0009-4536 |
| DOI: | 10.1002/jccs.201700137 |
| Popis: | A series of tetra(biphenyl-4-yl)phthalimide (TBPPI) derivatives with different N-substituents (n-butyl, phenyl, p-methyl phenyl, and p-acetyl phenyl moieties for compounds 7–10, respectively) were prepared to examine their fluorescent behavior under various conditions. The chemical structure of compound 7 has been successfully confirmed by single crystal X-ray diffraction analysis. The photoluminescence (PL) spectra in different ratios of CH2Cl2/EtOH mixture solutions revealed that compounds 7 and 8 exhibited both aggregation-induced emission (AIE) and aggregation-caused quenching (ACQ) behaviors, while compounds 9 and 10 displayed AIE and aggregation-induced emission enhancement (AIEE) properties, respectively. |
| Databáze: | OpenAIRE |
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