Studies of Tertiary Amine Oxides. Part115. Carbon - 13 nuclear magnetic resonance spectra of some N-(4-substituted phenyl) piperidine, the corresponding N-oxides, and their thermal-rearrangement product
Autor: | Abdul-Hussain Khuthier, Salim Y. Hanna, Jasim M. A. Al-Rawi |
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Rok vydání: | 1989 |
Předmět: | |
Zdroj: | Spectroscopy Letters. 22:549-560 |
ISSN: | 1532-2289 0038-7010 |
DOI: | 10.1080/00387018908053904 |
Popis: | The carbon-13 chemical shifts of seven N-(4-substituted phenyl) piperidine; the corresponding N-oxides, and their thermal rearrangement products were analyzed and assigned. The N-oxidation effect on the carbon-13 chemical shift is discussed, a correlation of N-oxidation effect with substituent constant (σp, σm, σI and σR) has been studied; dual substituent-parameter equation produce better correlation. |
Databáze: | OpenAIRE |
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