Studies of Tertiary Amine Oxides. Part115. Carbon - 13 nuclear magnetic resonance spectra of some N-(4-substituted phenyl) piperidine, the corresponding N-oxides, and their thermal-rearrangement product

Autor: Abdul-Hussain Khuthier, Salim Y. Hanna, Jasim M. A. Al-Rawi
Rok vydání: 1989
Předmět:
Zdroj: Spectroscopy Letters. 22:549-560
ISSN: 1532-2289
0038-7010
DOI: 10.1080/00387018908053904
Popis: The carbon-13 chemical shifts of seven N-(4-substituted phenyl) piperidine; the corresponding N-oxides, and their thermal rearrangement products were analyzed and assigned. The N-oxidation effect on the carbon-13 chemical shift is discussed, a correlation of N-oxidation effect with substituent constant (σp, σm, σI and σR) has been studied; dual substituent-parameter equation produce better correlation.
Databáze: OpenAIRE