Autor: Wilberth J. J. Smeets, Gerard A. van Albada, Jan Reedijk, Anthony L. Spek
Rok vydání: 2000
Předmět:
Zdroj: Journal of Chemical Crystallography. 30:441-444
ISSN: 1074-1542
DOI: 10.1023/a:1011339214337
Popis: The compound [Fe(bipym)33](CF3SO3)2 (in which bipym = 2,2′-bipyrimidine) crystallizes in the space group P21/c, with a = 13.7641(11), b = 18.7557(19), c = 12.3627(11) A, β = 103.085(8)° and Z = 4. The low-spin Fe(II) atom is octahedrally surrounded by six nitrogen atoms of three bipyrimidine groups with Fe—N distances that vary from 1.968(4) to 1.975(4) a. In the far-infrared region the Fe—N vibrations are observed at 359 and 372 cm-1.
Databáze: OpenAIRE
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