BATCH AND SEMIBATCH REACTORS MODELLING AND VALIDATION BASED ON ON-LINE pH MEASUREMENT

Autor:	M. D. Grau, L. Puigjaner
Rok vydání:	2000
Předmět:	Chromatography Chemistry Differential equation General Chemical Engineering Nuclear engineering Batch reactor Thermal Energy balance Water cooling General Chemistry Conductivity Ph measurement Line (formation)
Zdroj:	Chemical Engineering Communications. 178:49-65
ISSN:	1563-5201 0098-6445
DOI:	10.1080/00986440008912176
Popis:	Based on on-line pH measurement, a comparative study between batch and semibalch reactors performance has been carried out in a glass-jacketed reactor of 51 provided with the measuring, data acquiring and controlling system. The reaction system chosen was an acid-base reaction, the concentrations of the species in the reactor were obtained simply by measuring the pH of reaction solution. Based on the conductivity profiles of the solution at different temperatures, the kinetic equation of this acid-base reaction was established. The thermal behaviors of batch reactor were investigated by heating and cooling water in the reactor. The dynamic behavior of batch reaction could be described by a set of differential equations resulting from the mass and energy balance of the reaction mixture, the energy balance of the jacket wall and the circulating fluid inside the jacket. This model has been validated with experimental results, and could be applied to the complex control situations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6794467be2d33cb311ad47e58c1719ac https://doi.org/10.1080/00986440008912176 Zobrazit plný text záznamu