Synthesis, structural characterization, and fluorescence of a series of 1D rare earth coordination polymers with a substituted iminodiacetate ligand
| Autor: | Smaragda Lymperopoulou, Vassilis Psycharis, Catherine P. Raptopoulou, Theodore Lazarides, C. A. Papachristodoulou, John C. Plakatouras |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Lanthanide
010405 organic chemistry Ligand Iminodiacetic acid Inorganic chemistry Supramolecular chemistry Infrared spectroscopy Crystal structure 010402 general chemistry 01 natural sciences Fluorescence spectroscopy 0104 chemical sciences Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry Isostructural |
| Zdroj: | Inorganica Chimica Acta. 472:276-282 |
| ISSN: | 0020-1693 |
| Popis: | The combination of the polycarboxylic ligand N-(4-carboxy-benzyl)iminodiacetic acid (LH3) with rare earth (RE) chlorides under hydrothermal conditions leads to the formation of 1D cationic coordination polymers formulated as {[RE(LH2)2(H2O)4]Cl}n [where RE = Y (1), Eu (2), Tb (3) and Yb (4)]. All compounds are isostructural and characterized with IR spectroscopy, and thermal (TG) studies. Compounds 1, 2 and 4 were characterized with single crystal X-ray diffraction while 2 and 3 with fluorescence spectroscopy. The ligand utilizes only two of the available for coordination carboxylates and the crystal structures are stabilized by an extended array of H-bonds that gives rise to a 3D supramolecular architecture. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect