Synthesis and structure of monomeric and solvent-free LPrX2 compounds supported by a new β-diketiminato ligand [L=Et2NCH2CH2NC(Me)CHC(Me)NCH2CH2NEt2, X=Cl, Br, BH4]
| Autor: | Hans-Georg Schmidt, Ana Mirela Neculai, Mathias Noltemeyer, Herbert W. Roesky, Jörg Magull, Dante Neculai |
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| Rok vydání: | 2002 |
| Předmět: |
Lanthanide
chemistry.chemical_classification 010405 organic chemistry Ligand Praseodymium Stereochemistry Organic Chemistry chemistry.chemical_element Halide Salt (chemistry) 010402 general chemistry Borohydride 01 natural sciences Biochemistry 0104 chemical sciences 3. Good health Inorganic Chemistry chemistry.chemical_compound Crystallography Monomer chemistry Materials Chemistry Lithium Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. :47-52 |
| ISSN: | 0022-328X |
| Popis: | Trivalent praseodymium complexes with a new β-diketiminato ligand, possessing two pendant arms, LPrX2, (X=Cl (3), Br (4), BH4 (5)), have been prepared by the reactions of the lithium salt of the ligand with the corresponding halides. X-ray structural and elemental analysis showed that 3, 4, and 5 are neutral, monomeric and solvent-free complexes. These complexes adopt a pseudo-octahedral geometry with the two X (X=Cl, Br, BH4) arranged in the trans positions. |
| Databáze: | OpenAIRE |
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